The brighter side of twisted polymers

Conjugated polymer-derived nanoparticles, called Pdots,

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are expected to transform several areas, including optoelectronics, bio-imaging, bio-sensing and nanomedicine, due to their intense fluorescence, high stability under exposure to light and low cytotoxicity. Their spectroscopic properties are tunable by tweaking the polymer structures. This makes it essential to consider their design at the molecular level.

Bio-imaging applications require nanoparticles small enough to be eliminated from the body and strongly emit light in the far-red to near-infrared range. However, current design and fabrication of Pdots have mostly relied on empirical approaches, hindering attempts to manufacture these ultrasmall nanoparticles.

To meet this challenge, Dr. Hubert Piwoski and Associate Professor Satoshi Habuchi came up with a systematic method that enhances the performance of Pdots. Habuchi explained that his team aimed to create Pdots of a smaller size and brighter fluorescence by using conjugated polymers, whose backbone of alternating single and multiple bonds enables so-called π electrons to move freely throughout the structure.

For the first time, the researchers opted for twisted, instead of planar, conjugated polymers as building blocks to generate their Pdots. Existing Pdots usually exhibit lower fluorescence intensity than their precursors as result of complex inter- and intra-chain photophysical interactions within particles.

Read more at: https://phys.org/news/2017-05-brighter-side-polymers.html#jCp