Elusive atomic motion captured by electron microscopy

said braka 12:56 AM
In some contexts, it is extremely important that

boundaries are maintained. One example is within thin film technology, which uses extremely thin films of various  stacked on top of each other. The thermally induced movement of atoms through a material, , is well-known. A specific sort of diffusion along linear defects in a material was proposed as early as the 1950s, but has remained a theoretical concept since then and researchers have never been able to observe it directly. Instead,  and indirect methods are commonly applied to measure that phenomenon, known as dislocation-pipe diffusion.
Researchers at Linköping University and the University of California in Berkeley have now finally been able to observe the migration of atoms between the layers of a thin film. They used scanning transmission electron microscopy (STEM) with such a high resolution that it was possible to image the positions of  in the material. The specimen they studied was a thin film in which layers of a metal, hafnium nitride (HfN), around 5 billionths of a metre thick, alternate with layers of a semiconductor, scandium nitride (ScN).
The properties of the HfN/ScN layers make this material a suitable candidate for use in, for example, coating technology and microelectronics. It is for stability reasons very important that the layers of metal and semiconductor do not mix. Problems arise if the atoms diffuse across an interlayer forming a closed bridge between the layers in the film, similar to an electric short circuit.
"The material we have studied acts as a perfect model system, but this type of diffusion occurs in nearly all materials. Metals and semiconductors are found in all the electronic components used in in mobile phones, computers, etc. This is why it is important that materials scientists understand this type of diffusion," says Magnus Garbrecht, associate senior lecturer in the Department of Physics, Chemistry and Biology at Linköping University.


Read more at: https://phys.org/news/2017-05-elusive-atomic-motion-captured-electron.html#jCp